The six-membered rings exhibit slightly distorted chair, extremely distorted chair and half-chair conformation respectively, and the five-membered ring exhibits an envelope conformation.
其中六元环分别呈现微扭曲的椅式构象、严重扭曲的椅式构象及半椅式构象;
All transition states, activation energies and potential curves of four possible reaction paths were obtained. It was found that the homolysis of n-no2 bond in five-membered ring is the initial step.
求得可能的四种不同热解反应通道的过渡态、活化能和位能曲线,发现其热解引发步骤为五元环上侧链n—NO2键的均裂。
This article reviews the ring opening reaction of five membered nitrogen containing heterocyclic compounds.
综述了近年来各种五元氮杂环的开环反应及其在有机合成中的应用。
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